If you can't see weekend days visible in your diary, you can add them to the diary view within Settings -> My Settings:

Under Diary Settings, check Show Whole Weekend in Diary or Show Saturday in Diary, depending on what you'd like to be visible:

Then in Working Hours specify what your working hours are over the weekend:

These are your personal settings and not practice-wide. If a colleague is planning on working weekends they will also need to make this change in My Settings.

Once this has been done, you'll see weekends visible in your diary, and be able to book appointments for these days as normal.
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